Monday, September 8, 2025

Vertebral column


 

Chromium (atomic number 24)

Chromium (atomic number 24) has a special electron configuration because it is more stable when half-filled dd-orbitals are present.

Step by step:

  1. Normally, following the order of filling, we would expect:

1s2  2s2  2p6  3s2  3p6  4s2  3d41s^2 \; 2s^2 \; 2p^6 \; 3s^2 \; 3p^6 \; 4s^2 \; 3d^4

  1. However, Chromium actually shifts one electron from the 4s orbital to the 3d orbital to achieve a half-filled 3d53d^5, which is very stable.

  2. Final electron configuration:

    Cr: 1s2  2s2  2p6  3s2  3p6  3d5  4s1\text{Cr: } 1s^2 \; 2s^2 \; 2p^6 \; 3s^2 \; 3p^6 \; 3d^5 \; 4s^1

    In shorthand (noble gas form):

    Cr: [Ar]  3d5  4s1\text{Cr: } [Ar] \; 3d^5 \; 4s^1
     This unusual arrangement happens because a half-filled dd-subshell (3d⁵) gives extra stability due to electron exchange energy and symmetrical distribution.